L'expertise d'UT2A est reconnue internationalement pour ses compétences dans le développement d’instrumentation et de méthodes analytiques. Le laboratoire valorise ses développements et travaux de recherche dans des revues scientifiques.
Strontium elemental and isotopic signatures of Bordeaux wines for authenticity and geographical origin assessment
Epova E.N., Bérail S., Séby F., Vacchina V., Bareille G., Médina B., Sarthou L., Donard O.F.X.
Food Chemistry, 2019, 1, 35-45
Cr(VI) and Cr(III) in milk, dairy and cereal products and dietary exposure assessment
Hernandez F., Bemrah N., Séby F., Noël L., Guérin T.
Food Additives and Contaminants – Part B Surveillance, 2019, (sous presse)
Autophagy is essential for optimal translocation of iron to seeds in Arabidopsis
Pottier M., Dumont J., Masclaux-Daubresse C., Thomine S.
Journal of Experimental Botany, 2019, 70, 859-869
Critical assessment of hexavalent chromium species from different solid environmental, industrial and food matrices
Séby F.,Vacchina V.
Trends in Analytical Chemistry, 2018, 104, 54-68
Quantification of SeMet and SeCys in biological fluids and tissues by liquid chromatography coupled to inductively coupled plasma mass spectrometry (HPLC-ICP MS)
Vacchina, V., Bierla, K., Spuznar, J., Lobinski, R.
Methods in Molecular Biology, 2018, 1661, 153-162
Total selenium quantification in biological samples by inductively coupled plasma mass spectrometry (ICP-MS)
Vacchina, V., Dumont, J.
Methods in Molecular Biology, 2018, 1661, 145-152
Quantitative analysis of mineral elements in commercial pineapple juices by inductively Coupled Plasma Mass Spectrometry
Karim, A.Y.A., Gbaguidi, M.A.N., Baltrons O., Séby F., Monperrus M., Soclo H.H., Donard O.F.X.
International Journal of Food Science and Biotechnology, 2018, 3, 60-69
Determination of the chromium(III) reduction mechanism during chromium electroplating
Del Pianta D., Frayret J., Gleyzes C., Cugnet C., Dupin J.C., Le Hecho I.
Electrochimica Acta, 2018, 234-241
Towards routine analysis of TiO2 (nano-)particle size in consumer products: Evaluation of potential techniques
De la Calle I., Menta M., Klein M., Maxit B., Séby F.
Spectrochimica Acta – Part B Atomic Spectroscopy, 2018, 147, 28-42
Study of the presence of micro- and nanoparticles in drinks and foods by multiple analytical techniques
De la Calle I., Menta M., Klein M., Séby F.
Food Chemistry, 2018, 266, 133-145
Understanding the influence of open-waste burning on urban aerosols using metal tracers and lead isotopic composition
Kumar S., Aggarwal S.G., Sarangi B., Malherbe J., Barre J.P.G., Séby F., Donard O.F.X.
Aerosol and Air Quality Research, 2018, 18, 2433-2446
Total As and As speciation from worldwide collected red wine samples
Vacchina V., Epova E.N., Bérail S., Médina B., Donard O.F.X., Séby F.
Food Additives and Contaminants – Part B Surveillance, 2018, 11, 286-292
Optimisation of selective alkaline extraction for Cr(VI) determination in dairy and cereal products by HPIC–ICPMS using an experimental design
Hernandez F., Séby F., Millour S., Noël L., Guérin T.
Food Chemistry, 2017, 113, 981-988
Screening of TiO2 and Au nanoparticles in cosmetics and determination of elemental impurities by multiple techniques (DLS, SP-ICP-MS, ICP-MS and ICP-OES)
De la Calle I., Menta M., Klein M., Séby F.
Talanta, 2017, 171, 291-306
Optimization and validation of the methods for the total mercury and methylmercury determination in breast milk
V. Vacchina, F. Séby, R. Chekri, J. Verdeil, J. Dumont, M. Hulin, V. Sirot, J-L. Volatier, R. Serreau, A. Rousseau, T. Simon, T. Guérin.
Talanta, 2017, 167, 404-410
Rapid ion-exchange matrix removal for a decrease of detection limits in the analysis of salt-rich reservoir waters for fluorobenzoic acids by liquid chromatography coupled with tandem mass spectrometry
Kubica P., Vacchina V., Wasilewski T., Reynaud S., Szpunar J., Lobinski R.
Analytical and Bioanalytical Chemistry, 2017, 409, 871-879
Development of an alternative analytical methodology to monitor industrial degreasing baths by dynamic light scattering
Menta M., Frayret J., Grassl B., Gleyzes C., Castetbon A., Potin-Gautier M.
Journal of Cleaner Production, 2016, 113, 981-988.
Beryllium in exhaled breath condensate as a biomarker of occupational exposure in primary production aluminium plant
Hulo S., Radauceanu A., Chérot-Kornobis N., Howsam M., Vacchina V., De Broucker V., Rousset D., Grzebyk M., Dziurla M., Sobaszek A., Edme J.L.
International Journal of Hygiene and Environmental Health, 2016, 219, 40-47
Current trends and challenges in sample preparation for metallic nanoparticles analysis in daily products and environmental samples: A review
De la Calle I., Menta M., Séby F.
Spectrochimica Acta – Part B Atomic Spectroscopy, 2016, 126, 66-96
Analyses de formes chimiques et de nanoparticules dans les échantillons d’eau : méthodes analytiques, préconcentration et validation
Séby F., Dumont J., Gleyzes C., Menta M., Vacchina V., Bueno M.
Revue des Sciences de l’Eau, 2015, 28, 27-32.
Cr(VI) speciation in foods by HPLC-ICP MS: investigation of Cr(VI)/food interactions by size exclusion and Cr(VI) determination and stability by ion-exchange on-line separations
Vacchina V., De la Calle I., Séby F.
Analytical and Bioanalytical Chemistry, 2015, 407, 3831-3839.
Thiomonas sp. CB2 is able to degrade urea and promote toxic metal precipitation in acid mine drainage waters supplemented with urea
Farasin J., Andres J., Casiot C., Barbe V., Faerber J., Halter D., Heintz D., Koechler S., Lièvremont D., Lugan R., Marchal M., Plewniak F., Séby F., Bertin P.N., Arsène-Ploetze F.
Frontiers in Microbiology, 2015, 6, doi: 10.3389/fmicb.2015.00993
Apport du couplage ETV-ICP/AES pour les analyses de spéciation dans le solide : cas de l’arsenic et du mercure
Frayret J., Gleyzes C.
Spectra Analyse 2015, 302, 49-56.
Résumé
Le couplage ETV-ICP/AES représente une alternative simple et rapide à mettre en oeuvre pour l’analyse directe totale d’éléments trace dans le solide par rapport à des méthodes nécessitant une mise en solution pouvant entraîner des facteurs de dilution, des biais et des contaminations. Ce couplage peut aussi être utilisé pour obtenir des informations de spéciation directement dans la matrice solide. Cette information peut être obtenue par séparation des différents composés grâce à leur température d’évaporation. Les étapes de préparation de l’échantillon généralement utilisées sont ainsi réduites au minimum avec uniquement une étape de broyage et d’homogénéisation, limitant ainsi les risques de modification de la spéciation et permettant une analyse simple et rapide. Une modification et une optimisation des conditions d’analyses par ETV et par ICP/AES permettent d’obtenir des informations sur les différentes formes chimiques de l’arsenic et du mercure.
Use of dried blood spots and inductively coupled plasma mass spectrometry for multi-element detection in blood
Vacchina V., Huin V., Hulo S., Cuny D., Broly F., Renom G., Perini J.-M.
Journal of Trace Elements in Medecine and Biology, 2014, 28, 255-259.
Zinc fate in animals husbandry systems
Romeo A., Vacchina V., Legros S., Doelsch E.,
Metallomics, 2014, 6, 1999-2009
Metagenomic insights into microbial metabolism affecting arsenic dispersion in Mediterranean marine sediments
Plewniak F., Koechler S., Navet B., Dugat-Bony E., Bouchez O., Peyret P., Séby F., Battaglia-Brunet F., Bertin P.N.
Molecular Ecology, 2013, 22, 4870-4883.
Comparative efficiency of a new organic selenium source vs. seleno-yeast and mineral selenium sources on muscle selenium enrichment and selenium digestibility in broiler chickens
Briens M., Mercier Y., Rouffineau F., Vacchina V., Geraert P.A.
British Journal of Nutrition, 2013, 110, 617-624.
Determination of Zn-, Cu- and Mn-glycinate complexes in feed samples and in-vitro and in-vivo assays to assess their bioaccessibility in feed samples
Vacchina V., Ionescu C., Oguey S., Lobinski R.
Talanta, 2013, 113, 14-18.
Arsenic in marina sediments from the Mediterranean coast: speciation in the solid phase and occurrence of thioarsenates
Mamindy-Pajany Y., Bataillard P., Séby F. , Crouzet C., Moulin A., Guezennec A.G., Hurel C., Marmier N., Battaglia-Brunet F.
Soil and Sediment Contamination, 2013, 22, 984-1002
Speciation of antimony in injectable drugs used for leishmaniasis (Glucantime) by HPLC-ICP MS and DPP
Séby F., Gleyzes C., Grosso O., Plau B., Donard O.F.X.
Analytical and Bioanalytical Chemistry, 2012, 404, 2939-2948.
Les méthodologies analytiques pour les analyses de spéciation
Séby F., Dumont J., Vacchina V.
Spectra Analyse, 2012, 287, 49-59.
Résumé
Cet article présente les techniques analytiques disponibles pour l’analyse de spéciation des éléments trace. Il est maintenant reconnu que la mesure de la concentration totale d’un élément ne permet pas d’obtenir d’information fiable sur son impact environnemental et sa toxicité. Seules les analyses de spéciation dont le principe est d’identifier et de doser les différentes formes chimiques des éléments permettent d’accéder à cette information. Cette approche nécessite de disposer de protocoles d’échantillonnage, de conservation et de préparation d’échantillon stricts qui ne modifient pas la répartition des formes chimiques. Ces protocoles sont détaillés dans cet article ainsi que les techniques instrumentales disponibles et leurs applications. Ces techniques sont la plupart du temps basées sur l’association en ligne d’une méthode séparative (méthodes chromatographiques) et d’une détection par spectrométrie atomique. Les principaux outils de validation et d’amélioration de la fiabilité des résultats (la dilution isotopique) sont détaillés.
Determination of organotin compounds in urine samples using GC-ICP-MS
Dumont J., Frery N., Vandentorren S., Séby F.
Agilent speciation handbook 2nd edition. 2012, 82-84.
Selenium exposure in subjects living in areas with high selenium concentrated drinking water: results of a French integrated exposure assessment survey
Barron E., Migeot V., Séby F., Ingrand I., Potin-Gautier M., Legube B., Rabouan S.
Environmental International, 2012, 40, 155-161
Development of an analytical method to monitor industrial degreasing and rinsing baths
Menta M., Frayret J., Gleyzes C., Castetbon A., Potin-Gautier M.
Journal of Cleaner Production, 2012, 20, 161–169
Evaluation of compost and mixture of compost and activated carbon as biofilter media for the treatment of indoor air pollution
Ondarts M., Hort C., Sochard S., Platel V., Moynault L., Séby F.
Environment Technology, 2012, 33, 273-284.
Evaluation of hexavalent chromium extraction method EPA method 3060A for soils using XANES spectroscopy
Malherbe J., Isaure M.-P., Séby F., Watson Russell P., Rodriguez-Gonzalez P., Stutzman P.E., Davis C.W., Maurizio C., Unceta N., Sieber J.R., Long S. E., Donard O.F.X.
Environmental Science and Technology, 2011, 45, 10492-10500
Unsuspected diversity of arsenite-oxidizing bacteria as revealed by widespread distribution of the aoxB gene in prokaryotes
Heinrich-Salmeron A., Cordi A., Brochier-Armanet C., Halter D., Pagnout C., Abbaszadeh-Fard E., Montaut D., Séby F., Bertin P.N., Bauda P., Arsene-Ploetze F.
Applied and Environmental Microbiology, 2011, 77, 4685-4692
Taxonomic and functional prokaryote diversity in mildly arsenic-contaminated sediments
Halter D., Cordi A., Gribaldo S., Gallien S., Goulhen-Chollet F., Heinrich-Salmeron A., Carapito C., Pagnout C., Montaut D., Séby F., Van Dorsselaer A., Schaeffer C., Bertin P.N., Bauda P., Arsene-Ploetze F.
Research in Microbiology, 2011, 162, 878-887.
Chromium speciation in solid matrices and regulation: a review
Unceta N., Séby F., Malherbe J., Donard O.F.X.
Analytical Bioanalytical Chemistry, 2010, 397, 1097-1111
Simultaneous speciation of selenomethionine and 2-hydroxy-4-methylselenobutanoic acid by HPLC – ICP MS in biological samples
Vacchina V., Moutet M., Yadan J.C., de Baene F., Kudla B., Lobinski R.
Journal of Chromatography B, 2010, 878, 1178-1180
Characterization of metal glycinate complexes by electrospray Q-TOF-MS/MS and their determination by capillary electrophoresis – ICP MS : application to premix samples
Vacchina V., Oguey S., Ionescu C., Bravo D., Lobinski R.
Analytical Bioanalytical Chemistry, 2010, 398, 435-449.
Chromium speciation in cement extracts and airborne particulates using HPLC coupled with ICP-MS
Mc Sheehy S., Séby F., Nash M.
Brazilian Journal of Analytical Chemistry, 2010, 1, 25-28
Résumé
A HPLC-ICP-MS method was developed to analyze trivalent and hexavalent chromium in cement extracts and airborne particulates. Method validation was performed using a NIST Certified Reference Material (CRM-545) and agreement between the measured and certified values was achieved. The determined method detection limits (MDLs) were 0.10 μg/kg for CrVI and 0.64 μg/kg for CrIII. The determined limits of quantification (LOQs) were 0.35 μg/kg for CrVI and 2.13 μg/kg for CrIII. The developed methodology allowed for sensitive and accurate chromium speciation in real samples of cement and dust extracts.
ICP-MS: Couplage plasma induit par haute fréquence – spectrométrie de masse
Paucot H., Potin-Gautier M.
Techniques de l’Ingénieur, 2010, P2720v2, 1-12
Sensitivity improvement in ICP MS analysis of fuels and light petroleum matrices using a microflow nebulizer and heated spray chamber sample introduction
Caumette G., Lienemann C.-P., Merdrignac I., Paucot H., Bouyssiere B., Lobinski R.
Talanta, 2009, 80, 1039-1043
The case for re-evaluating the upper limit value for selenium in drinking waters in Europe
Barron E., Migeot V., Rabouan S., Potin-Gautier M., Séby F., Hartemann P., Levi Y., Legube B.
Journal of Water and Health, 2009, 7, 630-641
Etude de l’évolution des formes chimiques des métaux dans des sédiments marins dragués stockés à terre
Séby F., Benoit-Bonnemason C., Tessier E., Alzieu C., Aqua J.L., Sannier L., Donard O.F.X.
PARALIA, 2009, 2, s3.1-s3.12
Total selenium and selenomethionine in pharmaceutical yeast tablets : assessment of the state of the art of measurements capabilities through international intercomparison CCQM-P86
Goenega-Infante H., Sturgeon R., Turner J., Hearn R., Sargent M., Maxwell P., Yang L., Barzev A., Pedrero Z., Camara C., Diaz Huerta V., Fernandez Sanchez M. L., Sanz-Medel A., Emese K., Fodor P., Wolf W., Goldschmidt R., Vacchina V., Szpunar J., Valiente L., Huertas R., Labarraque G., Davis C., Zeisler R., Turk G., Rizzio E., Mackay L. G., Myors R. B., Saxby D. L., Askew S., Chao W., Jun W.
Analytical Bioanalytical Chemistry, 2008, 390, 629-642
Determination of selenocysteine and selenomethionine in edible animal tissues by 2D size-exclusion reversed-phase HPLC – ICP MS following carbamidomethylation and proteolytic extraction
Bierla K., Dernovics M., Vacchina V., Szpunar J., Bertin G., Lobinski R.
Analytical Bioanalytical Chemistry, 2008, 390, 1789-1798
Simultaneous derivatization of selenocysteine and selenomethionine in animal blood prior to their specific determination by 2D size-exclusion ion-pairing reversed-phase HPLC – ICP MS
Bierla K., Vacchina V., Szpunar J., Bertin G., Lobinski R.
Journal of Analytical Atomic Spectrometry, 2008, 23, 508-513
Methylmercury exposure assessment using dietary and biomarker data among frequent seafood consumers in France – CALYPSO Study
Sirot V., Guérin T., Mauras Y., Garraud H., Volatier J.-L., Leblanc J.-C.
Environmental Research, 2008, 107, 30-38
Development of analytical procedures for the determination of hexavalent chromium in corrosion preventing coatings used in automotive industry
Séby F., Castetbon A., Ortega R., Guimon C., Niveau F., Barrois-Oudin N., Garraud H., Donard O.F.X.
Analytical and Bioanalytical Chemistry, 2008, 391, 587-597
Méthodologies analytiques pour la spéciation des métaux dans les produits de la mer dans le cadre d’une approche bénéfice/risque (étude CALIPSO)
Garraud H., Vacchina V., Séby F., Dumont J., Sirot V., Guérin T., Leblanc J.-C.
Annales de Toxicologie Analytique, 2007, XIX, 71-80
Techniques de détermination d’espèces chimiques d’éléments (spéciation) dans l’environnement
Séby F., Donard O.F.X.
Techniques de l’Ingénieur, 2007, P3 870v2, 1-24
Determination of hexavalent chromium in cement by the use of HPLC-ICP-MS, FPLC-ETAAS, spectrophotometry and selective extraction techniques
Scancar J., Milacic R., Séby F., Donard O.F.X.
Journal of Analytical Atomic Spectrometry, 2005, 9, 871-875
Partitioning of metal species during an enriched fuel combustion experiment. Speciation in the gaseous and particulate phases
Pavageau M.P., Morin A., Séby F., Guimon C., Krupp E., Pécheyran C., Donard O.F.X.
Environmental Science and Technology, 2004, 38, 2252-2263
Methodological advances for selenium speciation analysis in yeast
Ruiz-Encinar J., Sliwka-Kaszynska M., Polatajko A., Vacchina V., Szpunar J.
Analytica Chimica Acta, 2003, 500, 171-183
Sensitive species-specific monitoring of a new triplatinum anti-cancer drug and its potential related compounds in spiked human plasma by cation-exchange HPLC - ICP MS
Vacchina V., Torti L. Allievi C., Lobinski R.
Journal of Analytical Atomic Spectrometry, 2003, 18, 884-890
Chromium speciation by hyphenation of high-performance liquid chromatography to inductively coupled plasma-mass spectrometry – Study of the influence of interfering ions
Séby F., Charles S., Gagean M., Garraud H., Donard O.F.X.
Journal of Analytical Atomic Spectrometry, 2003, 18, 1386-1390
Developments of analytical procedures for determination of total chromium by quadrupole ICP-MS and high-resolution ICP-MS, and hexavalent chromium by HPLC-ICP-MS, in different materials used in automotive industry
Séby F., Gagean M., Garraud H., Castetbon A., Donard O.F.X.
Analytical and Bioanalytical Chemistry, 2003, 377, 685-694
Sorption behaviour of caesium on a bentonite sample
Hurel C., Marmier N., Séby F., Giffaut E., Bourg A.C.M., Fromage F.
Radiochimica Acta, 2002, 90, 695-698
A critical review of thermodynamic data for selenium species at 25°C
Séby F., Potin-Gautier M., Giffaut E., Borge G., Donard O.F.X.
Chemical Geology, 2001, 171, 173-194
A critical review of thermodynamic data for inorganic tin species
Séby F., Potin-Gautier M., Giffaut E., Donard O.F.X.
Geochimica et Chimica Acta, 2001, 65, 3041-3053
Production and use of reference materials for environmental analyses: conclusions of a workshop
De Guillebon B., Pannier F., Séby F., Bennink D., Quevauviller P.
Trends in Analytical Chemistry, 2001, 20, 160-166